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I think I'd use the purpose built chemicals. Dunno about charcoal. Shouldn't be harmful unless you pulled it out of some old fire pit, but I think I'd file it away in the back of mind for use in the backcountry if/when you don't have purpose built chemicals with you. Not really worth saving...

That isn't something I'd worry about. If you're pulling out a tourniquet, things are pretty dire. As long as it isn't on too long, I think the damage is fixable.

This is my stuff... Never know when you'll need some quick pepperoni :^P That's just to keep stuff dry. I have some clotting powder, an Israeli bandage, a rats tourniquet, and there might be some little stuff like bandaids for nuisance stuff. Can't remember. I should see what I have.