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Ethanol is made in a plant, no where near the pipeline hubs. Your gasoline and diesel are shipped via pipeline from refineries to a centralized hub for the area, and it's stored in large tanks. Trucks haul in ethanol and additives, and these are also placed in tanks. Then the fuel tanker trucks...

Methanol is added in a small percentage to make it poisonous, so it can't be taxed at the beverage rate. It's called denaturing.